Hi Callum,
You should be able to use those batteries but it wont be ideal. Those batteries are pretty heavy, the huge capacity will help you with the range of your car but you have a low voltage of 48V. I plan on using 156V in my project and using 40-50Ah batteries to get me 40-40mile range. Lower voltage means that your motor will produce less rpm meaning that your top rpm will be lower. I think you should use those batteries as a test bed for now and get sealed lead acid (SLAs) once the car is done.
Suren
Another point to make regarding the voltage, is that the higher the Voltage - the LOWER the Amperage needed for the same power! This means that the cables used to provide power to the motor, battery interconnects, switch gear etc, can be thinner and will run cooler, than if you are using a lower voltage. This will be cheaper and MUCH more easy to route the cables.
Still requires heavy duty stuff, mind - but it will not be as heavy a guage wire as you would need to use at low voltage to get the same power from the motor.
48V is doable though, though I would be tempted to run the 48v traction motor at a higher voltage, say 72V wich it should be able to tollerate OK. This will require six 12V batteries in series (to increase voltage), and the same number in parallel (to provide more current) or even more - depending on the Ahr (current) rating of the batteries used. Depending of the control gear, this too may be able to handle the higher voltage - but you will need to confirm this first. 72V is quite common voltage to use, so switchgear is available for this voltage.
Also I mentioned AGM batteries (Absorbed Glass Mat - electrlyte (acid) is absorbed in glass fibre, not gell or liquid), these are a type of sealed lead-acid battery, simmilar to an "SLA" type battery -
BUT are the ones you should use, as opposed to standard SLA types (which are usually gelled electrolyte). There are many advantages to AGM over standard SLA types, the primary one being the ability to handle higher current delivery, and handle abuse better - so are better suited to motive use.
The battery banks you have at work, are gelled electrolyte types, but I belive these are NOT sealed - I think they have vent caps and may require monitoring of water levels (as I said, rail batteries are not my thing - so not 100% on all deatails).
As said above, they would be ideal as a testbed for the vehicle - so would be worth a risk.

SS