I have had alloy 4 pot calipers on a few cars now, but they were mainly for fast road/trackday stuff. I was thinking more about saving unsprung weight than any real braking improvement. but I have to say the braking was improved.
pulling to the side when braking can be down to a tracking/alignment issue, or as stated already tie rod bushes etc, but if you know the pistons in the calipers are rusty, they could well be causing those symptoms.
do I think they are worth fitting in your instance, I think it depends how long you plan to keep the car, and if you are planning power upgrades in the future.