Nice idea. I also initially thought there may be an issue with emmisions, but thinking about it the test is initially conducted only at tick over when clearly the pressure in the inlet manifold will be much lower than at the exhaust. Just be mindful thought that if your car is '72 onwards the above, catch tanks and the like may fall foul of C&U regs.
Run catch tanks in all my performance cars, all sailed through MOT's. Including the VTA ones I've had on the Evos.
Not something that would get tested on an MOT.
Relevant legislation:
"The engine shall be equipped with means sufficient to ensure that, while the engine is running, any vapours or gases in the engine crank case, or in any other part of the engine to which vapours or gases may pass from that case, are prevented, so far as is reasonably practicable, from escaping into the atmosphere otherwise than through the combustion chamber of the engine."
Not something that will concern many I'm sure, but worth a mention.