Matthew, ChopperHarris is correct. The Mk1 horn did not use a relay and was permanently "hot" with the horn push providing a ground/earth path.
You should be able to find a generic dash mounted horn push button at a larger auto parts store. They were very common in the 1970s... not so much today.
At the slam panel in the front of the car you need to look for two wires, a purple wire and a purple/black wire. The purple wire (if still connected on the far end) will be a permanently hot supply to one side of the horn. The purple black should go off to the interior of the car and is normally run up the steering column under the shroud to the slip ring behind the steering wheel. To use your aftermarket switch, the purple/black wire at the slam panel is connected to the second horn terminal and when the end in the car is earthed, the horn will sound. For the aftermarket switch you would connect the purple/black to one switch terminal and a black earth wire to the other horn terminal. That's the basic wiring without a relay.
If you want to add the relay, buy a generic Bosch/ISO 30A or 40A relay at the parts store. The purple and purple black wires would be connected to the relay coil's terminals. For power you would then run a fused wire from the solenoid or fuse box to one of the relay's power terminals. The other relay power terminal would need a wire run to a horn terminal and finally the remaining horn terminal is connected to earth/ground.