Yes, copper will react with E10 fuel, and cause lots of problems downstream, but from the point of view of the fairly low pressure in the fuel system should be safe. It does need to be anchored down tight, as it is subject to fatigue fracture if it is allowed to vibrate.
In brake systems, copper as such is just plain unsafe, as it will not withstand sufficient number of full pressure brake applications without fatigue failure, even if the vibration aspect has been dealt with. Kunifer (copper/nickel alloy) is the stuff to use, and can be recognised as it is a lot harder that copper when it comes to bending or flaring, and has a reddish-grey tinge, copper being red.
Copper is illegal in exhaust systems, and although it is possible that it is not mentioned in the current version of the Construction & Use Regs (no need now, no-one uses it, why would they want to?), the problem was that it tended to react with certain combustion products to form explosive compounds, or so it was said. I think it was banned in about 1920. It also suffers badly from localised corrosion pitting due to chloride ions (as in salt!), especially when stressed, not what you would want in either a brake or fuel system.